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【Chemical Name】 Tetrabutylphosphonium bromide
Tetrabutylphosphonium bromide is a quaternary ammonium salt derivative, where the ammonium group is replaced by a phosphonium center. This compound features a central phosphorus atom surrounded by four butyl (C4H9-) groups, forming a positively charged ion, which is counterbalanced by a bromide (Br-) anion.
Structure:
The molecular structure of tetrabutylphosphonium bromide can be represented as [P(C4H9)4]+Br-. The phosphorus atom is at the center of a tetrahedral geometry, bonded to four butyl groups, each of which consists of a methyl group attached to a propyl chain.
Properties:
Physical State: White or yellowish crystal.
Solubility: Soluble in organic solvents, particularly nonpolar solvents like toluene and dichloromethane.
Stability: Stable under normal conditions, but may be sensitive to moisture and strong oxidizing agents.
Applications:
Tetrabutylphosphonium bromide finds applications in various fields due to its unique properties as a phase transfer catalyst, ionic liquid component, and reagent in organic synthesis. Some of its primary uses include:
Phase Transfer Catalysis: It is widely used as a phase transfer catalyst in reactions where it facilitates the transfer of ions from one phase (typically aqueous) to another (organic solvent), enhancing reaction rates and yields.
Ionic Liquids: It can be incorporated into the design of ionic liquids, which are salts that are liquid at room temperature. These liquids exhibit unique properties such as negligible vapor pressure, high thermal stability, and tunable physicochemical properties, making them attractive for applications in electrochemistry, separation processes, and catalysis.
Organic Synthesis: As a reagent, it participates in various organic reactions, such as nucleophilic substitutions, alkylations, and phosphorylations, often enhancing their efficiency and selectivity.
【Chemical Name】 Tetrabutylphosphonium bromide
Tetrabutylphosphonium bromide is a quaternary ammonium salt derivative, where the ammonium group is replaced by a phosphonium center. This compound features a central phosphorus atom surrounded by four butyl (C4H9-) groups, forming a positively charged ion, which is counterbalanced by a bromide (Br-) anion.
Structure:
The molecular structure of tetrabutylphosphonium bromide can be represented as [P(C4H9)4]+Br-. The phosphorus atom is at the center of a tetrahedral geometry, bonded to four butyl groups, each of which consists of a methyl group attached to a propyl chain.
Properties:
Physical State: White or yellowish crystal.
Solubility: Soluble in organic solvents, particularly nonpolar solvents like toluene and dichloromethane.
Stability: Stable under normal conditions, but may be sensitive to moisture and strong oxidizing agents.
Applications:
Tetrabutylphosphonium bromide finds applications in various fields due to its unique properties as a phase transfer catalyst, ionic liquid component, and reagent in organic synthesis. Some of its primary uses include:
Phase Transfer Catalysis: It is widely used as a phase transfer catalyst in reactions where it facilitates the transfer of ions from one phase (typically aqueous) to another (organic solvent), enhancing reaction rates and yields.
Ionic Liquids: It can be incorporated into the design of ionic liquids, which are salts that are liquid at room temperature. These liquids exhibit unique properties such as negligible vapor pressure, high thermal stability, and tunable physicochemical properties, making them attractive for applications in electrochemistry, separation processes, and catalysis.
Organic Synthesis: As a reagent, it participates in various organic reactions, such as nucleophilic substitutions, alkylations, and phosphorylations, often enhancing their efficiency and selectivity.
